Appendix III
PROHIBITED ARYLAMINE COMPOUNDS IN FINAL LEATHER, TEXTILE AND COATED FABRIC MATERIALS
Included here are the substances listed in Entry 43 of Annex XVII to Regulation (EC) No 1907/2006 that shall be tested for in any dyed leather (using the EN 17234 standard) or textiles (using the EN 14362-1 and -3 standards).
Table 1
Carcinogenic arylamines to be tested in textiles or leather.
|
Aryl amine |
CAS Number |
Aryl amine |
CAS Number |
|
4-aminodiphenyl |
92-67-1 |
4,4′-oxydianiline |
101-80-4 |
|
Benzidine |
92-87-5 |
4,4′-thiodianiline |
139-65-1 |
|
4-chloro-o-toluidine |
95-69-2 |
o-toluidine |
95-53-4 |
|
2-naphtylamine |
91-59-8 |
2,4-diaminotoluene |
95-80-7 |
|
o-amino-azotoluene |
97-56-3 |
2,4,5-trimethylaniline |
137-17-7 |
|
2-amino-4-nitrotoluene |
99-55-8 |
4-aminoazobenzene |
60-09-3 |
|
4-chloroaniline |
106-47-8 |
o-anisidine |
90-04-0 |
|
2,4-diaminoanisol |
615-05-4 |
2,4-Xylidine |
95-68-1 |
|
4,4′-diaminodiphenylmethane |
101-77-9 |
2,6-Xylidine |
87-62-7 |
|
3,3′-dichlorobenzidine |
91-94-1 |
p-cresidine |
120-71-8 |
|
3,3′-dimethoxybenzidine |
119-90-4 |
3,3′-dimethylbenzidine |
119-93-7 |
|
3,3′-dimethyl-4,4′-diaminodiphenylmethane |
838-88-0 |
4,4'-methylene-bis-(2-chloro-aniline) |
101-14-4 |
A number of other dye compounds, which are not directly restricted by Entry 43 of Annex XVII to Regulation (EC) No 1907/2006, are known to cleave during processing to form some of the prohibited substances listed in Table 1. In order to greatly reduce uncertainty about compliance with the established limit of 30 mg/kg for the substances listed in Table 1, manufacturers are recommended, but not obliged, to avoid the use of the dyes listed in Table 2.
Table 2
Indicative list of dyes that may cleave to form carcinogenic arylamines
|
Disperse dyes |
Basic dyes |
||
|
Disperse Orange 60 |
Disperse Yellow 7 |
Basic Brown 4 |
Basic Red 114 |
|
Disperse Orange 149 |
Disperse Yellow 23 |
Basic Red 42 |
Basic Yellow 82 |
|
Disperse Red 151 |
Disperse Yellow 56 |
Basic Red 76 |
Basic Yellow 103 |
|
Disperse Red 221 |
Disperse Yellow 218 |
Basic Red 111 |
|
|
Acid dyes |
|||
|
CI Acid Black 29 |
CI Acid Red 4 |
CI Acid Red 85 |
CI Acid Red 148 |
|
CI Acid Black 94 |
CI Acid Red 5 |
CI Acid Red 104 |
CI Acid Red 150 |
|
CI Acid Black 131 |
CI Acid Red 8 |
CI Acid Red 114 |
CI Acid Red 158 |
|
CI Acid Black 132 |
CI Acid Red 24 |
CI Acid Red 115 |
CI Acid Red 167 |
|
CI Acid Black 209 |
CI Acid Red 26 |
CI Acid Red 116 |
CI Acid Red 170 |
|
CI Acid Black 232 |
CI Acid Red 26:1 |
CI Acid Red 119:1 |
CI Acid Red 264 |
|
CI Acid Brown 415 |
CI Acid Red 26:2 |
CI Acid Red 128 |
CI Acid Red 265 |
|
CI Acid Orange 17 |
CI Acid Red 35 |
CI Acid Red 115 |
CI Acid Red 420 |
|
CI Acid Orange 24 |
CI Acid Red 48 |
CI Acid Red 128 |
CI Acid Violet 12 |
|
CI Acid Orange 45 |
CI Acid Red 73 |
CI Acid Red 135 |
|
|
Direct dyes |
|||
|
Direct Black 4 |
Direct Blue 192 |
Direct Brown 223 |
Direct Red 28 |
|
Direct Black 29 |
Direct Blue 201 |
Direct Green 1 |
Direct Red 37 |
|
Direct Black 38 |
Direct Blue 215 |
Direct Green 6 |
Direct Red 39 |
|
Direct Black 154 |
Direct Blue 295 |
Direct Green 8 |
Direct Red 44 |
|
Direct Blue 1 |
Direct Blue 306 |
Direct Green 8.1 |
Direct Red 46 |
|
Direct Blue 2 |
Direct Brown 1 |
Direct Green 85 |
Direct Red 62 |
|
Direct Blue 3 |
Direct Brown 1:2 |
Direct Orange 1 |
Direct Red 67 |
|
Direct Blue 6 |
Direct Brown 2 |
Direct Orange 6 |
Direct Red 72 |
|
Direct Blue 8 |
Basic Brown 4 |
Direct Orange 7 |
Direct Red 126 |
|
Direct Blue 9 |
Direct Brown 6 |
Direct Orange 8 |
Direct Red 168 |
|
Direct Blue 10 |
Direct Brown 25 |
Direct Orange 10 |
Direct Red 216 |
|
Direct Blue 14 |
Direct Brown 27 |
Direct Orange 108 |
Direct Red 264 |
|
Direct Blue 15 |
Direct Brown 31 |
Direct Red 1 |
Direct Violet 1 |
|
Direct Blue 21 |
Direct Brown 33 |
Direct Red 2 |
Direct Violet 4 |
|
Direct Blue 22 |
Direct Brown 51 |
Direct Red 7 |
Direct Violet 12 |
|
Direct Blue 25 |
Direct Brown 59 |
Direct Red 10 |
Direct Violet 13 |
|
Direct Blue 35 |
Direct Brown 74 |
Direct Red 13 |
Direct Violet 14 |
|
Direct Blue 76 |
Direct Brown 79 |
Direct Red 17 |
Direct Violet 21 |
|
Direct Blue 116 |
Direct Brown 95 |
Direct Red 21 |
Direct Violet 22 |
|
Direct Blue 151 |
Direct Brown 101 |
Direct Red 24 |
Direct Yellow 1 |
|
Direct Blue 160 |
Direct Brown 154 |
Direct Red 26 |
Direct Yellow 24 |
|
Direct Blue 173 |
Direct Brown 222 |
Direct Red 22 |
Direct Yellow 48 |